生物脫硫技術(shù)借助微生物的代謝作用，將含硫化合物轉(zhuǎn)化為無害或易處理的物質(zhì)，相比傳統(tǒng)化學(xué)脫硫，具有能耗低、二次污染少、適用范圍廣等特點，廣泛應(yīng)用于沼氣凈化、工業(yè)尾氣處理、 wastewater 治理等領(lǐng)域，是實現(xiàn)硫化物資源化與無害化的重要綠色技術(shù)路徑。

　　Biological desulfurization technology utilizes the metabolic process of microorganisms to convert sulfur-containing compounds into harmless or easily treatable substances. Compared with traditional chemical desulfurization, it has the characteristics of low energy consumption, less secondary pollution, and wide applicability. It is widely used in fields such as biogas purification, industrial exhaust gas treatment, and wastewater treatment, and is an important green technology path to achieve sulfide resource utilization and harmless treatment.

　　生物脫硫的核心原理是微生物的氧化還原反應(yīng)，不同菌種分工完成硫的轉(zhuǎn)化。硫氧化細(xì)菌是主要功能菌群，在有氧或厭氧條件下，通過呼吸作用將硫化物作為能量來源：在好氧環(huán)境中，硫化氫被氧化為單質(zhì)硫或硫酸根；在厭氧環(huán)境中，某些細(xì)菌可利用硝酸鹽作為電子受體，將硫化物氧化為硫單質(zhì)，同時將硝酸鹽還原為氮氣，同步實現(xiàn)脫氮脫硫。微生物的代謝活性受環(huán)境影響顯著，最適溫度為 25-35℃，pH 值需維持在 6.5-8.0，溶解氧濃度根據(jù)菌種類型控制。

　　The core principle of biological desulfurization is the oxidation-reduction reaction of microorganisms, and different bacterial strains divide the labor to complete the conversion of sulfur. Sulfur oxidizing bacteria are the main functional microbial community that use sulfides as an energy source through respiration under aerobic or anaerobic conditions. In aerobic environments, hydrogen sulfide is oxidized to elemental sulfur or sulfate ions; In anaerobic environments, certain bacteria can use nitrate as an electron acceptor to oxidize sulfides into elemental sulfur, while reducing nitrate to nitrogen gas, achieving simultaneous denitrification and desulfurization. The metabolic activity of microorganisms is significantly affected by the environment, with an optimal temperature of 25-35 ℃ and a pH value of 6.5-8.0. The dissolved oxygen concentration is controlled according to the type of bacterial strain.

　　預(yù)處理系統(tǒng)為微生物反應(yīng)創(chuàng)造適宜條件，是工藝穩(wěn)定運行的基礎(chǔ)。含硫氣體或液體進(jìn)入脫硫系統(tǒng)前，需先去除雜質(zhì)：氣體中若含粉塵，需經(jīng)旋風(fēng)分離器或濾袋過濾，防止堵塞生物膜載體；液體中若含重金屬，需通過沉淀或吸附去除。對高濃度含硫氣體，需進(jìn)行稀釋至 5% 以下，避免濃度過高對微生物產(chǎn)生毒性。溫度調(diào)節(jié)也至關(guān)重要，低溫原料需預(yù)熱，高溫原料需冷卻，確保反應(yīng)體系溫度穩(wěn)定。

　　The pre-treatment system creates suitable conditions for microbial reactions and is the foundation for stable operation of the process. Before entering the desulfurization system, sulfur-containing gases or liquids need to remove impurities: if the gas contains dust, it needs to be filtered through a cyclone separator or filter bag to prevent clogging of the biofilm carrier; If heavy metals are present in the liquid, they need to be removed through precipitation or adsorption. For high concentration sulfur-containing gases, it is necessary to dilute them to below 5% to avoid toxicity to microorganisms caused by excessive concentration. Temperature regulation is also crucial. Low temperature raw materials need to be preheated, while high-temperature raw materials need to be cooled to ensure the temperature stability of the reaction system.

　　核心反應(yīng)裝置是微生物發(fā)揮作用的場所，其結(jié)構(gòu)設(shè)計直接影響脫硫效率。生物濾池是最常用的反應(yīng)器類型，內(nèi)部填充多孔載體，微生物在載體表面形成生物膜，含硫氣體從底部進(jìn)入，與生物膜充分接觸，硫化氫去除率可達(dá) 95% 以上。生物滴濾池則通過循環(huán)噴淋液保持載體濕潤，適用于處理負(fù)荷波動大的場景。厭氧生物反應(yīng)器多用于液體脫硫，通過厭氧菌群將有機(jī)硫轉(zhuǎn)化為硫化氫，再進(jìn)一步氧化為單質(zhì)硫，有機(jī)硫去除率≥90%，尤其適合高濃度有機(jī)硫廢水處理。

　　The core reaction device is the place where microorganisms exert their effects, and its structural design directly affects the desulfurization efficiency. Biofilters are the most commonly used type of reactor, filled with porous carriers. Microorganisms form biofilms on the surface of the carriers, and sulfur-containing gases enter from the bottom and fully contact with the biofilms. The removal rate of hydrogen sulfide can reach over 95%. The biological drip filter uses circulating spray to keep the carrier moist, making it suitable for handling scenarios with large load fluctuations. Anaerobic bioreactors are commonly used for liquid desulfurization, converting organic sulfur into hydrogen sulfide through anaerobic bacterial communities, and further oxidizing it to elemental sulfur. The organic sulfur removal rate is ≥ 90%, making it particularly suitable for the treatment of high concentration organic sulfur wastewater.

　　產(chǎn)物分離與回收實現(xiàn)硫資源的循環(huán)利用，提升工藝經(jīng)濟(jì)性。反應(yīng)生成的單質(zhì)硫以顆粒形式存在，通過沉淀、過濾或離心分離從反應(yīng)體系中提取，純度可達(dá) 90% 以上，可作為化工原料。若產(chǎn)物為硫酸鹽，需通過結(jié)晶或生物還原進(jìn)行處理，避免直接排放導(dǎo)致水體富營養(yǎng)化。氣體產(chǎn)物經(jīng)脫硫后，凈化氣中硫化氫濃度可降至 10ppm 以下，滿足燃燒或排放要求。

　　The separation and recovery of products achieve the recycling of sulfur resources and improve the economic efficiency of the process. The elemental sulfur generated by the reaction exists in particle form and is extracted from the reaction system through precipitation, filtration, or centrifugal separation. The purity can reach over 90% and it can be used as a chemical raw material. If the product is sulfate, it needs to be treated through crystallization or bioreduction to avoid direct discharge and eutrophication of the water body. After desulfurization, the concentration of hydrogen sulfide in the purified gas can be reduced to below 10ppm, meeting the requirements for combustion or emissions.

　　工藝控制與優(yōu)化需兼顧微生物活性與處理效率。通過在線監(jiān)測系統(tǒng)實時采集反應(yīng)溫度、pH 值、溶解氧、硫化氫濃度等參數(shù)，當(dāng) pH 值低于 6.5 時，自動添加堿性物質(zhì)調(diào)節(jié)；溶解氧不足時，增大曝氣強(qiáng)度；脫硫效率下降 10% 以上時，檢查菌群活性，必要時補(bǔ)充菌種。營養(yǎng)鹽需定期補(bǔ)充，避免因氮、磷缺乏導(dǎo)致菌群生長受限。對于間歇運行的系統(tǒng)，重啟前需先通入低濃度含硫氣體，逐步激活微生物，再恢復(fù)正常負(fù)荷。

　　Process control and optimization need to balance microbial activity and treatment efficiency. Real time collection of reaction temperature, pH value, dissolved oxygen, hydrogen sulfide concentration and other parameters through an online monitoring system. When the pH value is below 6.5, alkaline substances are automatically added for adjustment; When the dissolved oxygen is insufficient, increase the aeration intensity; When the desulfurization efficiency decreases by more than 10%, check the activity of the microbial community and supplement the bacterial strains if necessary. Nutrients need to be regularly supplemented to avoid limiting bacterial growth due to nitrogen and phosphorus deficiency. For systems that operate intermittently, low concentration sulfur-containing gas should be introduced before restarting to gradually activate microorganisms and then restore normal load.

　　生物脫硫技術(shù)的優(yōu)勢在低濃度、復(fù)雜成分的硫處理中尤為突出，但其反應(yīng)速率低于化學(xué)法，因此更適合中低負(fù)荷場景。未來通過基因工程改造高效菌種、開發(fā)新型反應(yīng)器、結(jié)合人工智能優(yōu)化運行參數(shù)，生物脫硫?qū)⒃谔幚硇?、成本控制、資源回收等方面實現(xiàn)突破，進(jìn)一步擴(kuò)大其在環(huán)保與能源領(lǐng)域的應(yīng)用范圍。

　　The advantages of biological desulfurization technology are particularly prominent in the treatment of low concentration and complex sulfur components, but its reaction rate is lower than that of chemical methods, making it more suitable for medium and low load scenarios. In the future, through genetic engineering to modify efficient bacterial strains, develop new reactors, and optimize operating parameters with artificial intelligence, biological desulfurization will achieve breakthroughs in treatment efficiency, cost control, resource recovery, and further expand its application scope in the fields of environmental protection and energy.

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